THEME: "Current and Emerging Trends in Materials Research and Engineering"
Poznan University of Technology, Poland
Title: Carbon-silicon hybrid as anode material in energy sources
Eng.
Marita Piglowska (graduated in 2021), current master student of Composites and
Nanomaterials at Poznan University of Technology. In her scientific carrier she
published 9 articles in international reviewed journals. She took part in 2
international conferences (presented topics: flammability of lithium-ion cells
(she won the prize for the best student oral presentation) and use fuel cells
and batteries in automotive industry). In 2019 she became the winner of the 2nd
place in Hydrogen Competition in Poland. In 2021 she won the Veolia contest for
the best engineering thesis and took part in Summer School of Veolia.
Graphite
is a commonly used active material in the anode of a lithium-ion cell. Its
biggest disadvantage is its limited specific capacity, which is 372 mAh g-1.
For this reason, more effective electrode materials have been sought for many
years - incl. oxide with transition elements, carbon, silicon. In a lithium-ion
cell, a capacity is sought, which is achieved by pure lithium, which cannot be
used as an anode due to its danger and cost. Due to the great interest in green
chemistry and an attempt to reduce waste from various industries, attempts are
made to apply carbon materials. As it is not possible to achieve all valuable
properties with the use of one material, composite and hybrid materials are
used. Hybrid materials can be defined as combinations of two (or more)
materials, of materials and space and composites are connected at the nanometer
or molecular level. They are assembled in such a way as to have attributes that
are not offered by any material separately. Using materials of natural origin
increases the biodegradability of the cell, contributes to spreading the slogan
of green chemistry, and also achieves high specific capacities after many
charge-discharge cycles. Silicon, in general, presents high specific capacity,
proper working potential, abundant availability, environmental friendliness.
Unfortunately, there are some disadvantages such as huge volume change,
unstable SEI, low conductivity, which could be fixed using natural carbon
materials (biomass-derived) in hybrid systems, which is the main focus of this
work.