THEME: "Exploring Critical Breakthroughs in Catalysis and Chemical Engineering"
1University of Southampton, United Kingdom.
Title: Green Surfactants and Sustainability
Rakshitha Srinivasan is an Advanced Chemical
Engineering postgraduate student at the University of Southampton. She was born
in India and raised in Oman and India. She worked as a Research Associate in a
skincare start-up company for over a year. She then briefly worked as a Process
Engineer in a petrochemical consultancy before moving to the United Kingdom to
pursue her master’s degree.
Growing up in the Middle East, she was always
passionate about pursuing a career in the petrochemical and energy sectors. She
wanted to prove the importance of chemical engineers in society. With the
current transitions with respect to energy and emphasis on sustainability,
Rakshitha wants to design innovative processes with safety considerations to
meet the current needs of the people and make life better for the upcoming
generations.
In her free time, she enjoys hiking, traveling and
practicing yoga.
In recent times there has been a huge rise in the
number of problems caused by surfactants. Surfactants are surface active agents
that reduce the interfacial tension between two surfaces. They have several
applications, and they are predominantly used in the laundry industry. Since
the use of conventional surfactants causes many environmental issues such as
water pollution, threat to aquatic life, climate change, etc., a shift towards
green and sustainable surfactants is required.
In order to emphasize the need for green surfactants,
a case study was chosen. The case study highlights the problems caused by
conventional surfactants which led to the foaming of a lake in India. The foams
were highly toxic and flammable and eventually caused a fire to break out over
the lake as a result of a spark. It was found that the foams contained a large
amount of methane gas which is highly inflammable. Samples of the lake water
were collected and studied. It was noticed that the lake’s surface tension was
much lower than that of pure water, this indicated the presence of surfactant
content. It was found that high levels of anionic surfactants along with
phosphorus content led to the foaming of the lake. Additionally, the study
showed that the BOD & COD levels surpassed the permissible limit.
From the case study, it is evident that green
surfactants are highly necessary to overcome the pollution caused by
conventional surfactants. Green surfactants are eco-friendly, plant-based
surfactants that are synthesized using the principles of green chemistry. Alkyl
Polyglucoside (APG) is one such surfactant that is popular. The raw material
consists of an alcohol and sugar which react to form APG. Since the raw
materials are plant-derived, it is biodegradable. It is less foaming and has a
good cleansing ability. Currently, the APG process uses vegetable oils and
wheat as raw materials. However, using these raw materials can be energy
intensive and lead to emissions.
Though green surfactants are gaining popularity, more
research is needed to develop surfactants with less energy consumption and aim
at zero emissions. One way to achieve this is by the use of innovative
catalysts. This will greatly affect the processing cost and the product cost,
making it a more affordable alternative in the future.