THEME: "Fostering Advancements in Nanoscience and Nanotechnology"
Southeast University, China
Title: TBA
Calcium sulfoaluminate
cement (CSA) produced through the collaborative utilization of solid wastes is
an effective way to realize the resource utilization of solid waste. In this
research, different states of Cr(VI), as a heavy metal with great
environmental toxicity, are introduced into sulfoaluminate cement. As a result, the introduction of 3% sodium chromate and potassium
dichromate increased the setting time of CSA to 47.2% and 117.9%. After
hydration for 7 days, chromium ion leaching experiments
were performed in different solutions. The
leaching concentration of chromium ions gradually increases with the
oscillation time and
remains basically unchanged after 12 hours. In NaCl
solution, the immobilization of Cr(VI) in CSA cement is the highest (20.3 mg/g)
but the lowest that in NaCO3 solution (14.2
mg/g). The research results confirmed that the chloride ions in the NaCl
solution promote the crystal growth of ettringite, thus facilitating the
immobilization of Cr(VI) ions in their lattice, while in NaCO3
solution, Cr(VI) ions are easily released due to CO32-
ions binding calcium ions in ettringite crystals but still maintain a high curing amount. Therefore, this work provides a
theoretical criterion for toxicity leaching and safety application in different
environments for calcium sulfoaluminate cement from
solid waste.