THEME: "Fostering Advancements in Nanoscience and Nanotechnology"
Shahid Chamran University, Iran
Title: Freeze Casting at ambient pressure: a step to facilitate the process of fabricating porous materials such as graphene-CNTs aerogels
Mohadeseh Madadi Jaberi is an
active researcher in the field of nanotechnology whose specialty lies in
fabrication of 2D and 3D materials. She received her Masters’ from Shahid
Chamran University of Ahvaz in Solid-State Physics in 2019. She was also the laboratory
assistant who taught physics laboratory courses to bachelor students.
Mohadeseh currently serves as technology and innovation expert at Science and Technology Park (STP). She is responsible for supervising research activities in the field of micro- and nano-products. Besides she provides R&D groups with the necessary assistance to develop novel materials and products in the field of nanotechnology. Mohadeseh has been involved in many national and international collaborations, including International Congress of Chemical Engineering and Petroleum Industry Students and 14th conference on Condensed Matter
Having unique electrical properties
and high compressibility, ultra-light graphene aerogels (~10 mg/cm3)
have found many applications in the fields of energy dissipation, conductive
sensors and oil absorbers. There are several methods to produce graphene
aerogels which are costly and require special laboratory equipment, meanwhile
ambient pressure drying will be a desirable alternative that obviate the need
of special tools if preserving the physical structure is possible. The key is ice
templating or freeze casting through unidirectional freezing which is applied
to produce porous materials at ambient pressure. Meanwhile,
carbon nanotubes are known as advanced materials with extremely high elastic
modulus, greater than 1 TPa, used as reinforcement agent in nanocomposites. The
way of reaping the benefits of graphene and carbon nanotubes properties is
using them simultaneously as a composite. In this research, graphene aerogels
and graphene/single-walled carbon nanotubes (G/SWCNTs) nanocomposite aerogels
were produced by freeze casting at ambient pressure without the need for vacuum
apparatus. The mechanical experiments showed that both aerogels can withstand a
strain up to 90%, but generally, G/SWCNTs aerogels have greater elasticity than
the pure graphene aerogels. It was found that graphene aerogels had better
electrical conductivity and a threshold voltage of approximately 2 V, below
which no electrical current could be established. The electrical current is
linearly proportional to the stress. Absorption capacity of crude oil,
gasoline, edible oil and ethanol by graphene and G/SWCNTs aerogels were
measured and found that the gasoline was sponged up the most by both aerogels. Moreover,
the highest absorption capacity of graphene and G/SWCNTs aerogels were measured
at 85.5 gg-1 and 30.5 gg-1, respectively.